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You can quickly get a list of VMs, the datastores they are using and the logical folder they are in through PowerCLI:

Get-VM | Select Name,@{N="Datastore";E={[string]::Join(',',(Get-Datastore -Id $_.DatastoreIdList | Select -ExpandProperty Name))}},@{N="Folder";E={$_.Folder.Name}}

Combine it with Export-CSV to export the results to a CSV file.

 
 
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